Number of the records: 1
Cation-pi interaction of Ag+ with [6]helicene: An experimental and theoretical study
- 1.0446298 - ÚOCHB 2016 RIV NL eng J - Journal Article
Makrlík, E. - Jaklová Dytrtová, Jana - Vaňura, P. - Sýkora, Jan - Církva, Vladimír - Storch, Jan
Cation-pi interaction of Ag+ with [6]helicene: An experimental and theoretical study.
Chemical Physics Letters. Roč. 633, Jul 16 (2015), s. 105-108. ISSN 0009-2614. E-ISSN 1873-4448
R&D Projects: GA ČR GP13-21409P; GA ČR GAP207/10/1124
Institutional support: RVO:61388963 ; RVO:67985858
Keywords : circular dichroism * amino acids * gas-phase
Subject RIV: CF - Physical ; Theoretical Chemistry
Impact factor: 1.860, year: 2015
By using electrospray ionization mass spectrometry (ESI-MS), it was proven that the univalent silver cation (Ag+) forms with [6]helicene (C26H16) the cationic complex species [Ag(C26H16)](+). Further, by means of the collision-induced dissociation (CID) experiments, the appearance energy (AE) of the proven complex was found to be 255.0 kJ mol(-1). Finally, applying quantum mechanical DFT calculations, the most probable structure of the resulting complex was derived.
Permanent Link: http://hdl.handle.net/11104/0248271
Number of the records: 1