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Frustrated Lewis pairs-assisted reduction of carbonyl compounds
- 1.0443293 - ÚOCHB 2016 RIV GB eng J - Journal Article
Marek, Aleš - Pedersen, M. H. F.
Frustrated Lewis pairs-assisted reduction of carbonyl compounds.
Tetrahedron. Roč. 71, č. 6 (2015), s. 917-921. ISSN 0040-4020. E-ISSN 1464-5416
Institutional support: RVO:61388963
Keywords : frustrated Lewis pairs * hydrogen activation * benzyl alcohol * tritium labeling * labeled compounds
Subject RIV: CC - Organic Chemistry
Impact factor: 2.645, year: 2015
An alternative and robust method for the reduction of carbonyl groups by frustrated Lewis pairs (FLPs) is reported in this paper. With its very mild reaction conditions, good to excellent yields, absolute regioselectivity and the non-metallic character of the reagent, it provides an excellent tool for H-1, H-2 as well as H-3 chemistry. It is a new strategy for the one-pot synthesis of aromatic alcohols selectively labeled with heavy isotopes of hydrogen.
Permanent Link: http://hdl.handle.net/11104/0246072
Number of the records: 1