0434487 - ÚACH 2015 RIV RU eng J - Journal Article
Loginov, D.A. - Miloserdov, A.M. - Starikova, ZA. - Holub, Josef - Kudinov, AR.
Synthesis and structure of (tricarbollide)iodide iridium complex [(eta-1-(BuNH)-N-t-1,7,9-C3B8H10)IrI2](2).
Russian Chemical Bulletin. Roč. 62, č. 5 (2013), s. 1268-1271. ISSN 1066-5285. E-ISSN 1573-9171
Institutional support: RVO:61388980
Keywords : iridium * metallacarboranes * tricarbollide
Subject RIV: CA - Inorganic Chemistry
Impact factor: 0.509, year: 2013 ; AIS: 0.113, rok: 2013
DOI: https://doi.org/10.1007/s11172-013-0175-1

Cyclooctadiene complex (eta-1-(BuNH)-N-t-1,7,9-C3B8H10)Ir(cod) (1) was obtained by the reaction of [(7-(BuNH)-N-t-7,8,9-C3B8H10)]Tl with [(cod)IrCl](2) in the presence of TlPF6. The reaction of 1 with I-2 gave diiodide [(eta-1-(BuNH)-N-t-1,7,9-C3B8H10)IrI2](2) (2a). According to the X-ray diffraction data, complex 2a has a dimeric structure with two bridging iodine atoms.
Permanent Link: http://hdl.handle.net/11104/0238518