Highly photoactive 2D titanium dioxide nanostructures prepared from lyophilized aqueous colloids of peroxo-polytitanic acid

0429129 - ÚACH 2015 RIV GB eng J - Journal Article
Šubrt, Jan - Pulišová, Petra - Boháček, Jaroslav - Bezdička, Petr - Pližingrová, Eva - Volfová, Lenka - Kupčík, Jaroslav
Highly photoactive 2D titanium dioxide nanostructures prepared from lyophilized aqueous colloids of peroxo-polytitanic acid.
Materials Research Bulletin. Roč. 49, JAN (2014), s. 405-412. ISSN 0025-5408. E-ISSN 1873-4227
R&D Projects: GA ČR GA203/09/1117
Institutional support: RVO:61388980
Keywords : Oxides * Layered compounds * Electron microscopy * Raman spectroscopy * X-ray diffraction
Subject RIV: CA - Inorganic Chemistry
Impact factor: 2.288, year: 2014

Reaction of hydrogen peroxide with suspensions of thoroughly washed precipitates obtained by neutralization of aqueous solution of titanyl sulfate with aqueous ammonia leads to transparent yellow liquids. In this way prepared colloid solution is a two phase system in which, beyond the water phase, also a liquid hydrated peroxo-polytitanic acid component is present. Freeze drying of this colloid liquid provides a foamy material consisting of thin foils of peroxo-polytitanic acid containing small but not negligible amount of chemically bound ammonia. These foams annealed at temperature above similar to 200 degrees C lose water, ammonia and excess of oxygen providing foamy amorphous oxide. At higher temperatures above similar to 280 degrees C the amorphous material crystallizes to anatase which transforms at temperatures >850 degrees C to rutile. The size and shape of the initial leaflets forming the foam is preserved up to similar to 900 degrees C. Slit shaped porosity is formed during annealing. We observed that the annealed material is highly photoactive, probably owing to highly anisotropic shape of anatase aggregates and their perfect crystallinity.
Permanent Link: http://hdl.handle.net/11104/0234306