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Vapor pressures of dimethylcadmium, trimethylbismuth, and tris(dimethylamino)antimony

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    0397576 - FZÚ 2014 RIV NL eng J - Journal Article
    Morávek, Pavel - Fulem, Michal - Pangrác, Jiří - Hulicius, Eduard - Růžička, K.
    Vapor pressures of dimethylcadmium, trimethylbismuth, and tris(dimethylamino)antimony.
    Fluid Phase Equilibria. Roč. 360, Dec (2013), s. 106-110. ISSN 0378-3812. E-ISSN 1879-0224
    R&D Projects: GA ČR GA13-15286S; GA MŠMT(CZ) LM2011026
    Institutional support: RVO:68378271
    Keywords : vapor pressure * dimethylcadmium * trimethylbismuth * tris(dimethylamino)antimony * sublimation and vaporization enthalpy
    Subject RIV: CF - Physical ; Theoretical Chemistry
    Impact factor: 2.241, year: 2013

    Vapor pressures of three metalorganic precursors, dimethylcadmium, trimethylbismuth, and tris(dimethylamino)antimony were measured using the static method in the technologically important temperature range from 258 to 323 K. The experimental data were fitted with the Clarke and Glew as well as the Antoine equation. The enthalpies of sublimation and vaporization were derived from the temperature dependence of vapor pressure. To our knowledge, this the first time that the vapor pressure measurements for tris(dimethylamino)antimony and crystalline dimethylcadmium are reported.
    Permanent Link: http://hdl.handle.net/11104/0225193

     
     
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