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Raman and IR phonons in ferroelectric Sr.sub.0.35./sub.Ba.sub.0.69./sub.Nb.sub.2./sub.O.sub.6.04./sub. single crystals

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    0391759 - FZÚ 2014 RIV GB eng J - Journal Article
    Buixaderas, Elena - Gregora, Ivan - Hlinka, Jiří - Dec, J. - Lukasiewicz, T.
    Raman and IR phonons in ferroelectric Sr0.35Ba0.69Nb2O6.04 single crystals.
    Phase Transitions. Roč. 86, 2-3 (2013), s. 217-229. ISSN 0141-1594. E-ISSN 1029-0338
    R&D Projects: GA ČR GAP204/10/0616
    Institutional research plan: CEZ:AV0Z10100520
    Keywords : ferroelectrics * Raman spectroscopy * IR spectroscopy * phonons * relaxors * tungsten-bronze materials
    Subject RIV: BM - Solid Matter Physics ; Magnetism
    Impact factor: 1.044, year: 2013

    IR and Raman spectra of strontium barium niobate (SBN) with 35% of Sr were measured in a broad interval of temperatures (20–800 K). Anomalies in the frequencies and intensities of some IR and Raman active phonons were observed. These modes are presumably related to Sr and Nb–O vibrations. This brings evidence that, apart from the order–disorder nature of the ferroelectric phase transition in SBN, there could be some ferroelectricity induced by cation displacements in the low Sr content samples.
    Permanent Link: http://hdl.handle.net/11104/0220726

     
     
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