Synthesis, crystal structure, antimicrobial activity and electrochemistry study of chromium(III) and copper(II) complexes based on semicarbazone Schiff base and azide ligands

0391607 - FZÚ 2014 RIV NL eng J - Journal Article
Shaabani, B. - Khandar, A.A. - Dušek, Michal - Pojarová, Michaela - Mahmoudi, F.
Synthesis, crystal structure, antimicrobial activity and electrochemistry study of chromium(III) and copper(II) complexes based on semicarbazone Schiff base and azide ligands.
Inorganica chimica acta. Roč. 394, JAN (2013), s. 563-568. ISSN 0020-1693. E-ISSN 1873-3255
Grant - others:AV ČR(CZ) AP0701
Program: Akademická prémie - Praemium Academiae
Institutional support: RVO:68378271
Keywords : antimicrobial activity * azide ligand * metal complex * Schiff base ligand * X-ray structure
Subject RIV: BM - Solid Matter Physics ; Magnetism
Impact factor: 2.041, year: 2013

A tridentate NNO donor Schiff base ligand HL=C5H4NCH=NNHCONH2 was obtained by condensation of pyridine 2-carbaldehyde with semicarbazide. The HL and azide ligands with Cr(III) and Cu(II) ions have been used to synthesize a dinuclear complex [Cr(L)(N3)(OCH3)]2 (1) and a coordination polymer complex [Cu(L)(N3)]n (2). The ligand, 1 and 2 were clearly characterised by elemental analysis, FT-IR, UV–Vis spectral studies and the structures of the 1 and 2, have been studied by single crystal X-ray diffraction analysis.
Permanent Link: http://hdl.handle.net/11104/0220613