Synthesis, characterization and crystal structure of N,N'-Bis(2,3-Dimethoxybenzylidene)-1,2-Diaminoethane

0369331 - FZÚ 2012 RIV US eng J - Journal Article
Khalaji, A.D. - Fejfarová, Karla - Dušek, Michal - Bijanzadeh, H.R.
Synthesis, characterization and crystal structure of N,N'-Bis(2,3-Dimethoxybenzylidene)-1,2-Diaminoethane.
Journal of Chemical Crystallography. Roč. 41, č. 12 (2011), 1955-1960. ISSN 1074-1542. E-ISSN 1572-8854
Institutional research plan: CEZ:AV0Z10100521
Keywords : Shiff bases * X-ray diffraction * Jana2006 * crystal structure * characterization
Subject RIV: BM - Solid Matter Physics ; Magnetism
Impact factor: 0.566, year: 2011

Synthesis and characterization of single crystals of a new organic Schiff-base derivative, N,N'-bis(2,3-dimethoxybenzylidene)-1,2-diaminoethane is reported. Good quality single crystals with size 10 mm x 1 mm x 1 mm were grown by slow evaporation technique from a methanol solution at room temperature. The grown crystals have been characterized by elemental analyses and functional groups were identified using FT-IR and 1H-NMR spectroscopy. Crystal structure of the title compound has been determined by single crystal X-ray diffraction. The title compound has a monoclinic symmetry, space group P21/c, lattice parameters are a = 4.4159(3) A, b = 14.2333(9) A, c = 15.0601(10) A, beta = 97.755(5)°, Z = 2, V = 937.91(11) A3.
Permanent Link: http://hdl.handle.net/11104/0203424