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Anion-free bambus[6]uril and its supramolecular properties
- 1.0366974 - FZÚ 2012 RIV DE eng J - Journal Article
Švec, J. - Dušek, Michal - Fejfarová, Karla - Štacko, P. - Klán, P. - Kaifer, A.E. - Li, W. - Hudečková, E. - Šindelář, V.
Anion-free bambus[6]uril and its supramolecular properties.
Chemistry - A European Journal. Roč. 17, č. 20 (2011), s. 5605-5612. ISSN 0947-6539. E-ISSN 1521-3765
Grant - others:AV ČR(CZ) AP0701
Program: Akademická prémie - Praemium Academiae
Institutional research plan: CEZ:AV0Z10100521
Keywords : anion receptors * halides * host-guest systems * macrocycles * supramolecular chemistry
Subject RIV: BM - Solid Matter Physics ; Magnetism
Impact factor: 5.925, year: 2011
Methods for the preparation of anion-free bambus[6]uril (BU6) are presented. They are based on the oxidation of iodide anion utilizing dark oxidation by hydrogen peroxide or photooxidation in the presence of titanium dioxide. A number of crystal structures of BU6 complexes with various anions were obtained. The influence of the anion size on the macrocycle diameter is discussed together with an unusual arrangement of the macrocycles into separate layers.
Permanent Link: http://hdl.handle.net/11104/0201781
Number of the records: 1