Synthesis and structural characterization of two new layered inorganic-organic hybrid zinc phosphites templated by cyclam: Zn(HPO.sub.3./sub.).sub.2./sub. . 0.5(C.sub.10./sub.H.sub.28./sub.N.sub.4./sub.) and Zn.sub.2./sub.(HPO.sub.3./sub.).sub.3./sub. . 0.5(C.sub.10./sub.H.sub.28./sub.N.sub.4./sub.)

0365655 - FZÚ 2012 RIV US eng J - Journal Article
Halime, I. - Bezgour, A. - Fahim, M. - Dušek, Michal - Fejfarová, Karla - Lachkar, M. - El Bali, B.
Synthesis and structural characterization of two new layered inorganic-organic hybrid zinc phosphites templated by cyclam: Zn(HPO₃)₂ . 0.5(C₁₀H₂₈N₄) and Zn₂(HPO₃)₃ . 0.5(C₁₀H₂₈N₄).
Journal of Chemical Crystallography. Roč. 41, č. 2 (2011), s. 223-229. ISSN 1074-1542. E-ISSN 1572-8854
Grant - others:AV ČR(CZ) AP0701
Program: Akademická prémie - Praemium Academiae
Institutional research plan: CEZ:AV0Z10100521
Keywords : hybrid phosphates * cyclam * wet chemistry * single crystal structure * IR spectroscopy
Subject RIV: BM - Solid Matter Physics ; Magnetism
Impact factor: 0.566, year: 2011

Using 1,4,8,11-tetraazacyclotetradecane (cyclam) as a template, two new layered zincophosphites were synthesized and characterized by single crystal X-ray diffraction. The two new compounds crystallize in the triclinic system with the space group P - 1. Both structures are described in terms of phosphometallic slabs hosting the cyclam cation.
Permanent Link: http://hdl.handle.net/11104/0200846