Synthesis and structural studies of a new class of quaternary ammonium salts, which are derivatives of cage adamanzane type aminal 1,3,6,8-tetraazatricyclo [4.3.1.1.sup.3,8./sup.]undecane (TATU)

0365631 - FZÚ 2012 RIV GB eng J - Journal Article
Rivera, A. - Sadat-Bernal, J. - Ríos-Motta, J. - Dušek, Michal - Palatinus, Lukáš
Synthesis and structural studies of a new class of quaternary ammonium salts, which are derivatives of cage adamanzane type aminal 1,3,6,8-tetraazatricyclo [4.3.1.1^3,8]undecane (TATU).
Chemistry Central Journal. Roč. 5, č. 55 (2011), 55/1-55/8. ISSN 1752-153X. E-ISSN 1752-153X
Grant - others:AV ČR(CZ) AP0701
Program: Akademická prémie - Praemium Academiae
Institutional research plan: CEZ:AV0Z10100521
Keywords : quaternary ammonium salts * adamanzane * X-ray diffraction
Subject RIV: BM - Solid Matter Physics ; Magnetism
Impact factor: 3.281, year: 2011

Novel mono N-alkyl quaternary ammonium salts (3a-f) were prepared using the Menschutkin reaction. The structures of these new salts were established using various spectral and electrospray ionization mass spectrometry (ESI-MS) analyses. Compound (3b) was also analyzed using X-ray crystallography. It was noted that alkyl chain length did not significantly affect the reaction because all employed alkyl iodide electrophiles reacted in a similar fashion with the aminal 1.
Permanent Link: http://hdl.handle.net/11104/0200825