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Direct observation of triple ions in aqueous solutions of nickel(II) sulfate: A Molecular link between gas phase and bulk behavior

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    0363851 - ÚOCHB 2012 RIV US eng J - Journal Article
    Schröder, Detlef - Ducháčková, L. - Tarábek, Ján - Karwowska, M. - Fijalkowski, K. J. - Ončák, Milan - Slavíček, Petr
    Direct observation of triple ions in aqueous solutions of nickel(II) sulfate: A Molecular link between gas phase and bulk behavior.
    Journal of the American Chemical Society. Roč. 133, č. 8 (2011), s. 2444-2451. ISSN 0002-7863. E-ISSN 1520-5126
    R&D Projects: GA ČR GA203/08/1487; GA MŠMT LC512; GA AV ČR KAN400400651
    Grant - others:European Research Council(XE) AdG HORIZOMS
    Institutional research plan: CEZ:AV0Z40550506; CEZ:AV0Z40400503
    Keywords : electrospray ionization * infrared spectroscopy * mass spectrometry * microhydration * nickel sulfate
    Subject RIV: CF - Physical ; Theoretical Chemistry
    Impact factor: 9.907, year: 2011

    Electrospray ionization of aqueous nickel(II) sulfate provides direct experimental evidence for the formation of triple ions of the type [Ni2(SO4)(H2O)n]2+ and [Ni(SO4)2]2-, whose existence in aqueous solution has previously been proposed based on relaxation spectroscopy.
    Permanent Link: http://hdl.handle.net/11104/0199494

     
     
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