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Effect of the Carboxylate Shift on the Reactivity of Zinc Complexes in the Gas Phase
0363624 - UOCHB-X 2012 RIV US eng J - Journal Article
Ducháčková, L. - Schröder, Detlef - Roithová, J.
Effect of the Carboxylate Shift on the Reactivity of Zinc Complexes in the Gas Phase.
Inorganic Chemistry. Roč. 50, č. 7 (2011), s. 3153-3158 ISSN 0020-1669
R&D Projects: GA ČR GA203/08/1487
Institutional research plan: CEZ:AV0Z40550506
Keywords : acetate * infrared multiphoton dissociation * mass spectrometry * zinc
Subject RIV: CA - Inorganic Chemistry
Impact factor: 4.601, year: 2011
The effect of different modes of the carboxylato ligands on the reactivity of gaseous zinc-acetate complexes is investigated by infrared multiphoton dissociation spectroscopy. In [(Imi)nZn(CH3COO)]+ complexes (Imi = imidazole, n = 1-3) the coordination changes from bi- to monodentate upon coordination of the third imidazole ligand ("carboxylate shift").
Permanent Link: http://hdl.handle.net/11104/0006535