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A Ferrier-Type Allylic Rearrangement of 3´-Deoxy-3´,4´-didehydronucleosides Mediated by DMF Dimethyl Acetal: Direct Access to 4´-Alkoxy-2´,3´-didehydro-2´,3´-dideoxynucleosides

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    0362805 - ÚOCHB 2012 RIV US eng J - Journal Article
    Petrová, Magdalena - Buděšínský, Miloš - Zborníková, Eva - Fiedler, Pavel - Rosenberg, Ivan
    A Ferrier-Type Allylic Rearrangement of 3´-Deoxy-3´,4´-didehydronucleosides Mediated by DMF Dimethyl Acetal: Direct Access to 4´-Alkoxy-2´,3´-didehydro-2´,3´-dideoxynucleosides.
    Organic Letters. Roč. 13, č. 16 (2011), s. 4200-4203. ISSN 1523-7060. E-ISSN 1523-7052
    R&D Projects: GA ČR GA203/09/0820; GA ČR GA202/09/0193; GA AV ČR KAN200520801; GA MŠMT(CZ) LC06077
    Institutional research plan: CEZ:AV0Z40550506
    Keywords : allylic rearrangement * DMF dimethyl acetal * 4´-alkoxy-2´,3´-didehydro-2´,3´-dideoxynucleosides
    Subject RIV: CC - Organic Chemistry
    Impact factor: 5.862, year: 2011

    A straightforward synthesis of epimeric 4'-alkoxy-substituted 2',3'-didehydro-2',3'-dideoxynucleosides via a DMF dimethyl acetal mediated allylic rearrangement of 3'-deoxy-3',4'-didehydronucleosides is described.
    Permanent Link: http://hdl.handle.net/11104/0199016

     
     
Number of the records: 1  

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