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Hydroxylation of nitro-(pentafluorosulfanyl)benzenes via vicarious nucleophilic substitution of hydrogen
- 1.0361469 - ÚOCHB 2012 RIV GB eng J - Journal Article
Beier, Petr - Pastýříková, Tereza
Hydroxylation of nitro-(pentafluorosulfanyl)benzenes via vicarious nucleophilic substitution of hydrogen.
Tetrahedron Letters. Roč. 52, č. 34 (2011), s. 4392-4394. ISSN 0040-4039. E-ISSN 1873-3581
R&D Projects: GA ČR GAP207/11/0344
Institutional research plan: CEZ:AV0Z40550506
Keywords : pentafluorosulfanyl group * vicarious nucleophilic substitution * hydroxylation
Subject RIV: CC - Organic Chemistry
Impact factor: 2.683, year: 2011
Para- and meta-nitro-(pentafluorosulfanyl)benzenes react with anions of cumyl hydroperoxide in the presence of t-BuOK in liquid ammonia to form nitro-(pentafluorosulfanyl)phenols. Their reduction with hydrogen in the presence of Raney-Nickel provides amino-(pentafluorosulfanyl)phenols.
Permanent Link: http://hdl.handle.net/11104/0198776
Number of the records: 1