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1,4-Addition of tetraethyl fluoromethylenebisphosphonate to alpha, beta-unsaturated compounds

  1. 1.
    0360880 - ÚOCHB 2012 RIV CH eng J - Journal Article
    Opekar, Stanislav - Beier, Petr
    1,4-Addition of tetraethyl fluoromethylenebisphosphonate to alpha, beta-unsaturated compounds.
    Journal of Fluorine Chemistry. Roč. 132, č. 5 (2011), s. 363-366. ISSN 0022-1139. E-ISSN 1873-3328
    R&D Projects: GA ČR GP203/08/P310
    Institutional research plan: CEZ:AV0Z40550506
    Keywords : 1,4-addition * phosphonates * fluorine
    Subject RIV: CC - Organic Chemistry
    Impact factor: 2.033, year: 2011

    Tetraethyl fluoromethylenebisphosphonate in the presence of cesium carbonate in DMF undergoes efficient 1,4-addition to Michael acceptors having terminal double bond such as alpha,beta-unsaturated ketones, esters, sulfones, sulfoxides, and phosphonates to yield the corresponding adducts (alpha-alkyl-alfa-fluoromethylenebisphosphonates) in good to excellent yields.
    Permanent Link: http://hdl.handle.net/11104/0198330

     
     
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