Number of the records: 1
Pd2+ and Cu2+ catalyzed oxidative cross-coupling of mercaptoacetylenes and arylboronic acids
- 1.0360102 - ÚOCHB 2012 RIV GB eng J - Journal Article
Henke, Adam - Šrogl, Jiří
Pd2+ and Cu2+ catalyzed oxidative cross-coupling of mercaptoacetylenes and arylboronic acids.
Chemical Communications. Roč. 47, č. 14 (2011), s. 4282-4284. ISSN 1359-7345. E-ISSN 1364-548X
R&D Projects: GA ČR GA203/08/1318
Grant - others:AV ČR(CZ) M200550908
Institutional research plan: CEZ:AV0Z40550506
Keywords : mercaptoacetylenes * oxidative cross-coupling * Cu/Pd catalysis
Subject RIV: CC - Organic Chemistry
Impact factor: 6.169, year: 2011
An oxidative thiolate scavenging concept in a metal catalyzed reaction is presented and demonstrated on the aerobic Pd and Cu catalyzed cross-coupling of mercaptoacetylenes with arylboronic acids. Synthetic value of the chemistry as the complementary tool to the Sonogashira protocol has been demonstrated on a series of functionalized mercaptoacetylene substrates.
Permanent Link: http://hdl.handle.net/11104/0197734
Number of the records: 1