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Hydration modes of an amphiphilic molecule 2: NMR, FTIR and theoretical study of the interactions in the system water–1,2-dimethoxyethane
- 1.0359963 - ÚMCH 2012 RIV NL eng J - Journal Article
Kříž, Jaroslav - Dybal, Jiří
Hydration modes of an amphiphilic molecule 2: NMR, FTIR and theoretical study of the interactions in the system water–1,2-dimethoxyethane.
Chemical Physics. Roč. 382, 1-3 (2011), s. 104-112. ISSN 0301-0104. E-ISSN 1873-4421
R&D Projects: GA ČR GA203/09/1478; GA ČR GAP205/11/1657
Institutional research plan: CEZ:AV0Z40500505
Keywords : hydrophobic hydration * dimethoxyethane * NMR
Subject RIV: CD - Macromolecular Chemistry
Impact factor: 1.896, year: 2011
Using 1H and 13C NMR spectra, PFG diffusion measurements and relaxations as well as FTIR spectra and DFT quantum-mechanical calculations, it was shown that the dimethoxyethane molecule becomes wrapped at higher water contents in a cooperative hydration envelope utilizing both H-O...H and C-H...O hydrogen bonds.
Permanent Link: http://hdl.handle.net/11104/0197632
Number of the records: 1