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Postsynthesis Transformation of Three-Dimensional Framework into a Lamellar Zeolite with Modifiable Architecture

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    0359152 - ÚFCH JH 2012 RIV US eng J - Journal Article
    Roth, Wieslaw Jerzy - Shvets, O. V. - Shamzhy, M. - Eliášová, Pavla - Kubů, Martin - Nachtigall, P. - Čejka, Jiří
    Postsynthesis Transformation of Three-Dimensional Framework into a Lamellar Zeolite with Modifiable Architecture.
    Journal of the American Chemical Society. Roč. 133, č. 16 (2011), s. 6130-6133. ISSN 0002-7863. E-ISSN 1520-5126
    R&D Projects: GA AV ČR KAN100400701; GA ČR GA104/09/0561; GA ČR GA203/08/0604; GA ČR GD203/08/H032
    Institutional research plan: CEZ:AV0Z40400503
    Keywords : postsynthesis transformation * zeolites * UTL framework
    Subject RIV: CF - Physical ; Theoretical Chemistry
    Impact factor: 9.907, year: 2011

    Mild treatment of zeolite UTL results in degradation of its structure with preservation of the initially present dense layers connected by D4R “bridges”. The lamellar product obtained through this 3D to 2D zeolite conversion has been structurally modified similar to methodologies applied to layered zeolite precursors, which show the opposite 2D to 3D zeolite transformation.
    Permanent Link: http://hdl.handle.net/11104/0196989

     
     
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