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Suspension polymerization of aniline hydrochloride in non-aqueous media
- 1.0359118 - ÚMCH 2012 RIV GB eng J - Journal Article
Konyushenko, Elena - Stejskal, Jaroslav - Trchová, Miroslava - Prokeš, J.
Suspension polymerization of aniline hydrochloride in non-aqueous media.
Polymer International. Roč. 60, č. 5 (2011), s. 794-797. ISSN 0959-8103. E-ISSN 1097-0126
R&D Projects: GA AV ČR IAA400500905; GA AV ČR IAA100500902
Institutional research plan: CEZ:AV0Z40500505
Keywords : conducting polymer * polyaniline * non-aqueous media
Subject RIV: CD - Macromolecular Chemistry
Impact factor: 1.902, year: 2011
The oxidation of aniline hydrochloride by ammonium peroxydisulfate in non-aqueous media was studied, when themonomer or oxidant or both were not completely soluble. Polyaniline was formed in acetone, methanol and toluene. Aniline oligomers only were produced in chloroform and n-butylacetate. No interaction of the monomer and the oxidant was observed in dimethylsulfoxide and N-methylpyrrolidone. UV-visible and Fourier transform infrared spectra were recorded in order to study themolecular structure of the final products. Conductivity was measured for conducting protonated forms and corresponding bases. An explanation of aniline hydrochloride oxidation in various organicmedia is offered.
Permanent Link: http://hdl.handle.net/11104/0006426
Number of the records: 1