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Low-band gap donor-acceptor copolymers containing thienothiadiazole units for photovoltaics

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    0358686 - ÚMCH 2012 RIV US eng J - Journal Article
    Cimrová, Věra - Kmínek, Ivan - Pavlačková, Petra - Výprachtický, Drahomír
    Low-band gap donor-acceptor copolymers containing thienothiadiazole units for photovoltaics.
    ECS Transactions. Roč. 33, č. 17 (2011), s. 119-127. ISSN 1938-5862.
    [ECS Meeting /218./. Las Vegas, 10.10.2010-15.10.2010]
    R&D Projects: GA MŠMT(CZ) 1M06031
    Institutional research plan: CEZ:AV0Z40500505
    Keywords : fluorene * thiophene * thienothiadiazole
    Subject RIV: BM - Solid Matter Physics ; Magnetism

    Optical, electrochemical and photovoltaic properties of novel donor-acceptor copolymers containing dithienylthienothiadiazole derivatives and 9,9-bis(2-ethylhexyl)fluorene or 2,5-diisopentoxybenzene units were studied. The copolymers exhibited long-wavelength absorption, and possess small optical bandgap in the range of 1.1 - 1.4 eV depending on copolymer units and alkyl side-chain nature and length. They exhibited ambipolar redox properties and electrochromism. Photovoltaic devices with bulk heterojunction made of blends of copolymers and fullerene derivatives were prepared. Effects of side-chain nature and length on photophysical properties are discussed.
    Permanent Link: http://hdl.handle.net/11104/0196647

     
     
Number of the records: 1  

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