New Apparatus for Gas Permeability, Diffusivity and Solubility Assessing in Dense Polymeric Membranes

0358619 - ÚCHP 2011 RIV NL eng J - Journal Article
Petričkovič, Roman - Setničková, Kateřina - Uchytil, Petr
New Apparatus for Gas Permeability, Diffusivity and Solubility Assessing in Dense Polymeric Membranes.
Journal of Membrane Science. Roč. 369, 1-2 (2011), s. 466-473. ISSN 0376-7388. E-ISSN 1873-3123
R&D Projects: GA MŠMT ME 889
Institutional research plan: CEZ:AV0Z40720504
Keywords : sorption * diffusion * gas permeability
Subject RIV: CF - Physical ; Theoretical Chemistry
Impact factor: 3.850, year: 2011

Apparatus for consecutive measurements of permeability, diffusivity and solubility of vapors in polymer film during a single experiment was developed. The main advantage of this sweeping-gas apparatus with a new type of a permeation cell is the possibility to determine an amount of permeates sorbed in a membrane in the steady state of a vapor permeation process without any need of manipulation with the membrane. Permeate sorption data in the steady state provide important information about transport mechanism in polymeric membranes. Performance of the cell is illustrated on an example of toluene vapor permeation measurements through a low-density polyethylene (LDPE) membrane at 30 degrees C. The new apparatus provides transport parameters with high sensitivity and good reproducibility. Errors in transport parameters determination directly attributable to this technique seldom exceed 7%.
Permanent Link: http://hdl.handle.net/11104/0006406