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Photodegradation of poly[methyl(phenyl)silylene] in the presence of modifying substances

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    0358498 - ÚMCH 2012 RIV DE eng J - Journal Article
    Kochalska, Anna - Nožár, Juraj - Nešpůrek, Stanislav - Peter, Jakub
    Photodegradation of poly[methyl(phenyl)silylene] in the presence of modifying substances.
    Macromolecular Symposia. Roč. 295, č. 1 (2010), s. 71-76. ISSN 1022-1360.
    [Prague Meetings on Macromolecules /73./ New Frontiers in Macromolecular Science: From Macromolecular Concepts of Living Matter to Polymers for Better Quality of Life. Prague, 05.07.2009-09.07.2009]
    R&D Projects: GA AV ČR KAN400720701; GA AV ČR IAA100100622; GA MŠMT OC 138
    Institutional research plan: CEZ:AV0Z40500505
    Keywords : lithography * photodegradation * polymer
    Subject RIV: BM - Solid Matter Physics ; Magnetism

    Efficiency of the photodegradation of poly[methyl(phenyl)silylene] can be increased by electron acceptor additives with unstable anion radicals. The best chain degradation yield was obtained using benzoyl peroxide as an additive. The model for the photodegradation process is supported by quantum chemical calculations.
    Permanent Link: http://hdl.handle.net/11104/0196523

     
     
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