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Time-resolved FTIR emission spectroscopy of Cu in the 1800-3800 cm(-1) region: transitions involving f and g states and oscillator strengths

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    0358326 - ÚFCH JH 2012 RIV GB eng J - Journal Article
    Civiš, Svatopluk - Matulková, Irena - Cihelka, Jaroslav - Kubelík, Petr - Kawaguchi, K. - Chernov, V. E.
    Time-resolved FTIR emission spectroscopy of Cu in the 1800-3800 cm(-1) region: transitions involving f and g states and oscillator strengths.
    Journal of Physics B-Atomic Molecular and Optical Physics. Roč. 44, č. 2 (2011), 025002. ISSN 0953-4075. E-ISSN 1361-6455
    R&D Projects: GA AV ČR IAA400400705; GA AV ČR KAN100500652
    Institutional research plan: CEZ:AV0Z40400503
    Keywords : metal poor stars * atomic data * FTIR emission spectroscopy
    Subject RIV: CF - Physical ; Theoretical Chemistry
    Impact factor: 1.875, year: 2011

    Time-resolved Fourier-transform spectroscopy was applied to the study of the emission spectra of Cu vapours in a vacuum (10(-2) Torr) produced in ablation of a Cu metal target by a high-repetition rate (1.0 kHz) pulsed nanosecond ArF laser (lambda = 193 nm, output energy of 15 mJ). The time-resolved infrared emission spectrum of Cu was recorded in the 1800-3800 cm(-1) spectral region with a resolution of 0.017 cm(-1). The time profiles of the measured lines have maxima at 18-20 mu s after a laser shot and display non-exponential decay with a decay time of 5-15 mu s. This study reports 17 lines (uncertainty 0.0003-0.018 cm(-1)) of Cu I not previously observed. This results in seven newly-found levels and revised energy values for 11 known levels (uncertainty 0.01-0.03 cm(-1)). We also calculate transition probabilities and oscillator strengths for several transitions involving the reported Cu levels.
    Permanent Link: http://hdl.handle.net/11104/0196407

     
     
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