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The first metallacarborane triple-decker complexes with a bridging pentaphospholyl ligand

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    0356240 - ÚACH 2011 RIV CZ eng J - Journal Article
    Loginov, D.A. - Vinogradov, M.M. - Starikova, ZA. - Petrovskii, PV. - Holub, Josef - Kudinov, AR.
    The first metallacarborane triple-decker complexes with a bridging pentaphospholyl ligand.
    Collection of Czechoslovak Chemical Communications. Roč. 75, č. 9 (2010), s. 981-993. ISSN 0010-0765
    R&D Projects: GA MŠMT LC523
    Institutional research plan: CEZ:AV0Z40320502
    Keywords : boranes * metallacarboranes * iron * sandwich compounds
    Subject RIV: CA - Inorganic Chemistry
    Impact factor: 0.853, year: 2010

    Visible light irradiation of cations [(Carb)Fe(eta-C6H6)](+) in the presence of Cp*Fe(eta-cyclo-P-5) affords the mu-pentaphospholyl triple-decker complexes [(Carb)Fe(mu-eta:eta-cyclo-P-5)FeCp*](+) (Carb = 9-SMe2-7,8-C2B9H10 (3a) and 1-t-BuNH-1,7,9-C3B8H10 (3b)). Structures of 3a- and 3b[Co(eta-7,8-C2B9H11)(2)] were determined by X-ray diffraction. Bonding in 3a, 3b and mononuclear building blocks was analyzed by energy decomposition analysis.
    Permanent Link: http://hdl.handle.net/11104/0194816

     
     
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