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The effect of the pH on the oxidative polymerization of aniline and the morphology and properties of the products
- 1.0355746 - ÚMCH 2011 RIV RU eng J - Journal Article
Sapurina, I. Yu. - Stejskal, Jaroslav
The effect of the pH on the oxidative polymerization of aniline and the morphology and properties of the products.
Russian Chemical Reviews. Roč. 79, č. 12 (2010), s. 1123-1143. ISSN 0036-021X. E-ISSN 1468-4837
R&D Projects: GA MŠMT ME 847
Institutional research plan: CEZ:AV0Z40500505
Keywords : polyaniline * conducting polymer * nanotubes
Subject RIV: CD - Macromolecular Chemistry
Impact factor: 2.346, year: 2010
The synthesis and properties of the most popular and widely used electrically conducting polymer, polyaniline, are considered. The proposed mechanisms of the molecular synthesis and self-assembly of macromolecules occurring during the polymerization agree with the large body of experimental data. The acidity of the reaction medium is demonstrated to affect the mechanism on aniline oxidative polymerization and the formation of various types of supramolecular structures, namely nanoglobules, nanofibres, nanotubes and microspheres.
Permanent Link: http://hdl.handle.net/11104/0006313
Number of the records: 1