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A Note on Scenarios of Metastable Water
- 1.0352918 - ÚCHP 2011 RIV CZ eng J - Journal Article
Jirsák, Jan - Nezbeda, Ivo
A Note on Scenarios of Metastable Water.
Collection of Czechoslovak Chemical Communications. Roč. 75, č. 5 (2010), s. 593-605. ISSN 0010-0765
R&D Projects: GA AV ČR IAA400720802; GA AV ČR IAA200760905; GA AV ČR IAA400720710
Institutional research plan: CEZ:AV0Z40720504
Keywords : metastable water * spinodal * scenarios
Subject RIV: CF - Physical ; Theoretical Chemistry
Impact factor: 0.853, year: 2010
A recently developed molecular-based equations of state for water are analyzed with respectto the behavior of the liquid spinodal curve. It is shown that all of them yield the spinodal exhibiting a minimum in accordance with Speedy’s stability-limit conjecture and with the behavior predicted by the accurate (but purely empirical) IAPWS-95 equation. It means that the considered equations of state give consistent results but qualitatively different from those resulting from available computer simulations, which yield a monotonic spinodal line.
Permanent Link: http://hdl.handle.net/11104/0192305
Number of the records: 1