Synthesis and Electrochemistry of Cyclopentadienyl Ferratricarbollides Substituted by Me and Ph Groups on the Cage Carbon Atoms

0352913 - ÚACH 2011 RIV DE eng J - Journal Article
Holub, Josef - Bakardjiev, Mario - Štíbr, Bohumil - Štěpnička, P. - Císařová, I.
Synthesis and Electrochemistry of Cyclopentadienyl Ferratricarbollides Substituted by Me and Ph Groups on the Cage Carbon Atoms.
European Journal of Inorganic Chemistry. -, č. 26 (2010), s. 4196-4200. ISSN 1434-1948. E-ISSN 1099-0682
R&D Projects: GA MŠMT LC523
Institutional research plan: CEZ:AV0Z40320502
Keywords : Iron * boron * carboranes
Subject RIV: CA - Inorganic Chemistry
Impact factor: 2.909, year: 2010

Neutral tricarbollide tautomers of general formula 7-tBuNH-8,9-R,R’-nido-7,8,9-C3B8H9 generated a series of very stable, twelve-vertex ferratricarbollides. Electrochemical studies revealed that the FeII/FeIII redox potentials are primarily affected by the type of the ferratricarbaborane cage and, to a lesser extent, by the Me and Ph substituents residing on the cage carbon atoms.
Permanent Link: http://hdl.handle.net/11104/0192300