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High-Band-Gap Polycrystalline Monolayers of a 12-Vertex p-Carborane on Au(111)
- 1.0352048 - ÚOCHB 2011 RIV US eng J - Journal Article
Wrochem von, F. - Scholz, F. - Gao, D. - Nothofer, H. G. - Yasuda, A. - Wessels, J. M. - Roy, S. - Chen, X. - Michl, Josef
High-Band-Gap Polycrystalline Monolayers of a 12-Vertex p-Carborane on Au(111).
Journal of Physical Chemistry Letters. Roč. 1, č. 24 (2010), s. 3471-3477. ISSN 1948-7185
Grant - others:NSF(US) CHE-0848477
Institutional research plan: CEZ:AV0Z40550506
Keywords : molecular structure * quantum chemistry * general theory
Subject RIV: CF - Physical ; Theoretical Chemistry
Impact factor: 0.000, year: 2010
We have observed that p-carboranes tethered to gold by thiolate linkers form polycrystalline monolayers which are incommensurate with the Au(111) substrate. The incommensurability results from the strong interactions between adjacent p-carborane cages (1.6 eV/molecule) and from the adlayer lattice spacing, which is defined by the cage diameter.
Permanent Link: http://hdl.handle.net/11104/0191650
Number of the records: 1