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T-Shaped Molecular Building Blocks by Combined Bridgehead and Bridge Substitution on Bicyclo[1.1.1]pentanes
- 1.0351981 - ÚOCHB 2011 RIV US eng J - Journal Article
Kaleta, J. - Michl, Josef - Mazal, C.
T-Shaped Molecular Building Blocks by Combined Bridgehead and Bridge Substitution on Bicyclo[1.1.1]pentanes.
Journal of Organic Chemistry. Roč. 75, č. 7 (2010), s. 2350-2356. ISSN 0022-3263. E-ISSN 1520-6904
R&D Projects: GA MŠMT ME09114
Grant - others:NSF(US) CHE0848477; NSF(US) OISE-0532040
Institutional research plan: CEZ:AV0Z40550506
Keywords : staffanes * molecular electronics
Subject RIV: CF - Physical ; Theoretical Chemistry
Impact factor: 4.002, year: 2010
Derivatives of bicyclo[1.1.1]pentane differentially substituted in bridgehead (1,3) and bridge (2,4) positions have been synthesized. They represent a new T-shaped structural module consisting of a rigid rod with a nearly freely rotating side arm, possibly useful as a molecular building block in syntheses of more complex covalent or supramolecular scaffolds useful in bottom-up construction of molecular level devices or materials.
Permanent Link: http://hdl.handle.net/11104/0191600
Number of the records: 1