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Dioxygen Reduction by Cobalt(II) Octaethylporphyrin at Liquid vertical bar Liquid Interfaces
- 1.0348914 - ÚFCH JH 2011 RIV DE eng J - Journal Article
Partovi-Nia, R. - Su, B. - Méndez, M. A. - Habermeyer, B. - Gros, C. P. - Barbe, J.-M. - Samec, Zdeněk - Girault, H. H.
Dioxygen Reduction by Cobalt(II) Octaethylporphyrin at Liquid vertical bar Liquid Interfaces.
ChemPhysChem. Roč. 11, č. 13 (2010), s. 2979-2984. ISSN 1439-4235. E-ISSN 1439-7641
R&D Projects: GA ČR(CZ) GA203/07/1257; GA MŠMT OC 177
Institutional research plan: CEZ:AV0Z40400503
Keywords : cobalt * electrocatalysis * liquid/liquid interfaces
Subject RIV: CG - Electrochemistry
Impact factor: 3.339, year: 2010
Oxygen reduction catalyzed by cobalt(II) (2,3,7,8,12,13,17,18-octaethylporphyrin) [Co(OEP)] at soft interfaces is studied by voltammetry and biphasic reactions. When Co(OEP) is present in a solution of 1,2-dichloroethane in contact. With an aqueous acidic solution, oxygen is reduced if the interface is positively polarized (water phase versus organic phase). This reduction reaction is facilitated when an additional electron donor, here ferrocene, is present in excess in the organic phase.
Permanent Link: http://hdl.handle.net/11104/0189302
Number of the records: 1