Syntheses of conjugated polymers for photonics

0348865 - ÚMCH 2011 RIV DE eng J - Journal Article
Výprachtický, Drahomír - Cimrová, Věra - Kmínek, Ivan - Pavlačková, Petra
Syntheses of conjugated polymers for photonics.
Macromolecular Symposia. Roč. 295, č. 1 (2010), s. 94-99. ISSN 1022-1360.
[Prague Meetings on Macromolecules /73./ New Frontiers in Macromolecular Science: From Macromolecular Concepts of Living Matter to Polymers for Better Quality of Life. Prague, 05.07.2009-09.07.2009]
R&D Projects: GA MŠMT(CZ) 1M06031
Institutional research plan: CEZ:AV0Z40500505
Keywords : cis and trans isomers * conjugated polymer * conjugated polyelectrolyte
Subject RIV: BM - Solid Matter Physics ; Magnetism

By the Suzuki coupling reaction of 9,9-dioctyl-2,7-bis(1,3,2-dioxaborinan-2-yl)fluorene (I) and 3,5-di-tert-butylphenyl 2,5-dibromobenzenesulfonate (II) the alternating poly{[9,9-dioctylfluoren-2,7-diyl]-alt-[2-(3,5-di-tert-butyl-phenoxysulfonyl)-1,4-phenylene]} (III) was synthesized and its alkaline hydrolysis gave the polyelectrolyte (IV). Monomers 2,5-dibromo-3-[2-(pyren-1-yl)vinyl]thiophene and 2,5-dibromo-3-[2-(quinolin-4-yl)vinyl)thiophene were prepared and copolymerized with I to afford poly{[9,9-dioctylfluoren-2,7-diyl]-alt-[3-(2-(pyren-1-yl)vinyl)thiophen-2,5-diyl]} (V) and poly{[9,9-dioctylfluoren-2,7-diyl]-alt-[3-(2-(quinolin-4-yl)-vinyl)thiophen-2,5-diyl] (VI), respectively. By the polycondensation reaction of I and of the prepared methyl 3-(2,7-dibromocarbazole-9-yl)propionate (VII) the new poly{[9,9-dioctylfluorene-2,7-diyl]-alt-[9-(2-methoxycarbonylethyl)carbazole-2,7-diyl]} (VIII) was synthesized and characterized.
Permanent Link: http://hdl.handle.net/11104/0189273