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Cu and Ag catalyzed oxidative arylthiation of terminal acetylenes

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    0348740 - ÚOCHB 2011 RIV GB eng J - Journal Article
    Henke, Adam - Šrogl, Jiří
    Cu and Ag catalyzed oxidative arylthiation of terminal acetylenes.
    Chemical Communications. Roč. 46, č. 36 (2010), s. 6819-6821. ISSN 1359-7345. E-ISSN 1364-548X
    Grant - others:AV ČR(CZ) M200550907
    Institutional research plan: CEZ:AV0Z40550506
    Keywords : oxidative acid * copper * cross-coupling
    Subject RIV: CC - Organic Chemistry
    Impact factor: 5.787, year: 2010

    A mild Cu or Ag catalyzed oxidative arylthiation of terminal acetylenes is introduced. The process, featuring metal catalyzed C–H bond activation as a key step, leads to the formation of highly substituted mercaptoacetylenes under unprecedented neutral conditions.
    Permanent Link: http://hdl.handle.net/11104/0189179

     
     
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