Selective Monoacylation of Ferrocene with Bulky Acylating Agents over Mesoporous Sieve AlKIT-5

0345802 - ÚFCH JH 2011 RIV DE eng J - Journal Article
Vitvarová, Dana - Voláková, Martina - Vlk, Josef - Vinu, A. - Štěpnička, P. - Čejka, Jiří
Selective Monoacylation of Ferrocene with Bulky Acylating Agents over Mesoporous Sieve AlKIT-5.
Chemistry - A European Journal. Roč. 16, č. 26 (2010), s. 7773-7780. ISSN 0947-6539. E-ISSN 1521-3765
R&D Projects: GA ČR GA104/07/0383; GA ČR GD203/08/H032
Institutional research plan: CEZ:AV0Z40400503
Keywords : acylation * aluminum * ferrocene
Subject RIV: CF - Physical ; Theoretical Chemistry
Impact factor: 5.476, year: 2010

Ferrocene acylation with bulky acylating agents (1-adamantoyl, benzoyl, 2-chlorobenzoyl, and cinnamoyl chlorides; and benzoic anhydride) catalyzed by AlKIT-5 mesoporous catalysts was investigated. AlKIT-5 catalysts with varying ratios of Si/Al were synthesized using tetraethoxysilane and aluminum isopropoxide as the structural building blocks and Pluronic F127 as a template under acidic conditions and were characterized in detail by X-ray powder diffraction, magic-angle spinning (MAS) NMR spectroscopy, sorption of nitrogen, energy-dispersive X-ray spectroscopy (EDS), SEM, TEM, and FTIR with pyridine as a probe molecule. The catalytic activity of the prepared AlKIT-5 catalysts in ferrocene acylation was shown to depend on the type of the acylating agent, thus likely reflecting the strength of interactions between the acyl source, the product, and the solid catalysts when the acylation reaction was carried out at 100 °C.
Permanent Link: http://hdl.handle.net/11104/0186991