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Preferential activation of primary C–H bonds in the reactions of small alkanes with the diatomic MgO+. cation
- 1.0345734 - ÚOCHB 2011 RIV DE eng J - Journal Article
Schröder, Detlef - Roithová, J. - Alikhani, E. - Kwapien, K. - Sauer, J.
Preferential activation of primary C–H bonds in the reactions of small alkanes with the diatomic MgO+. cation.
Chemistry - A European Journal. Roč. 16, č. 13 (2010), s. 4110-4119. ISSN 0947-6539. E-ISSN 1521-3765
R&D Projects: GA AV ČR KJB400550704; GA ČR GA203/08/1487
Grant - others:ERC(XE) HORIZOMS AdG226373
Institutional research plan: CEZ:AV0Z40550506
Keywords : alkanes * C-H activation * density functional calculations * magnesium oxide
Subject RIV: CF - Physical ; Theoretical Chemistry
Impact factor: 5.476, year: 2010
The C-H bond activation of small alkanes by the gaseous MgO+ cation is probed by mass spectrometric methods. In the initial step, a pronounced kinetic control leads to the preferential attack of primary C-H bonds.
Permanent Link: http://hdl.handle.net/11104/0186937
Number of the records: 1