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Tailoring the Selectivity for Electrocatalytic Oxygen Evolution on Ruthenium Oxides by Zinc Substitution

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    0345022 - ÚFCH JH 2011 RIV DE eng J - Journal Article
    Petrykin, Valery - Macounová, Kateřina - Shlyakhtin, O. A. - Krtil, Petr
    Tailoring the Selectivity for Electrocatalytic Oxygen Evolution on Ruthenium Oxides by Zinc Substitution.
    Angewandte Chemie - International Edition. Roč. 49, č. 28 (2010), s. 4813-4815. ISSN 1433-7851. E-ISSN 1521-3773
    R&D Projects: GA AV ČR IAA400400906
    Institutional research plan: CEZ:AV0Z40400503
    Keywords : electrocatalysis * ruthenium oxides * zinc substitution
    Subject RIV: CG - Electrochemistry
    Impact factor: 12.730, year: 2010

    Versatile control of the selectivity of an oxide electrocatalyst in the oxygen- and chlorineevolution reactions was demonstrated by Zn substitution in RuO2 (see picture: O red, Cl green, Zn blue, Ru white). The incorporation of Zn into the rutile structure alters the cation sequence along the [001] direction and modifies the structure of the active sites for both gas-evolution processes.
    Permanent Link: http://hdl.handle.net/11104/0186400

     
     
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