Fluorescent nanodiamonds: effect of surface termination

0342773 - FZÚ 2011 RIV US eng C - Conference Paper (international conference)
Kratochvílová, Irena - Taylor, A. - Kovalenko, Alexander - Fendrych, František - Řezáčová, V. - Petrák, Václav - Záliš, Stanislav - Šebera, Jakub - Nesládek, Miloš
Fluorescent nanodiamonds: effect of surface termination.
Diamond Electronics and Bioelectronics - Fundamentals to Applications III. Warrendale, PA: Materials Research Society, 2010 - (Bergonzo, P.; Butler, J.; Jackman, R.; Loh, K.; Nesladek, M.), 1203-J03-05 /5 s. MRS Symposium Proceedings, Vol. 1203. ISBN 978-1-60511-176-6.
[MRS Fall Meeting 2009. Boston (US), 26.11.2009-02.12.2009]
R&D Projects: GA ČR GA203/08/1594; GA AV ČR KAN401770651; GA MŠMT OC 137; GA AV ČR KAN200100801; GA AV ČR KAN100400702
Institutional research plan: CEZ:AV0Z10100520; CEZ:AV0Z40400503
Keywords : nanodiamonds * surface termination * fluorescence
Subject RIV: BM - Solid Matter Physics ; Magnetism
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Hydrogen chemisorption on a chemical vapor deposition grown diamond surface is well-known to be important for stabilizing diamond surface structures with sp3 hybridization. Negative electron affinity condition could change to a positive electron affinity by oxidation of the H chemisorbed diamond surfaces. Oxidized diamond surfaces usually show characteristics completely different from those of the H-chemisorbed diamond surfaces. The unique electron affinity condition, or the surface potential, is strongly related to the chemisorbed species on diamond surfaces. The relationship between the surface chemisorption structure and the surface electrical properties, such as the surface potential of the diamond, has been modelled using DFT based calculations.
Permanent Link: http://hdl.handle.net/11104/0185408