Number of the records: 1
Oxygen and proton reduction by decamethylferrocene in non-aqueous acidic media
- 1.0342760 - ÚFCH JH 2011 RIV GB eng J - Journal Article
Su, B. - Hatay, I. - Ge, P. Y. - Méndez, M. A. - Corminboeuf, C. - Samec, Zdeněk - Ersöz, M. - Girault, H. H.
Oxygen and proton reduction by decamethylferrocene in non-aqueous acidic media.
Chemical Communications. Roč. 46, č. 17 (2010), s. 2918-2919. ISSN 1359-7345. E-ISSN 1364-548X
R&D Projects: GA ČR(CZ) GA203/07/1257; GA MŠMT OC 177
Institutional research plan: CEZ:AV0Z40400503
Keywords : ferrocene derivatives * liquid interface * perchloric acid
Subject RIV: CG - Electrochemistry
Impact factor: 5.787, year: 2010
Experimental studies and density functional theory (DFT) computations suggest that oxygen and proton reduction by decamethylferrocene (DMFc) in 1,2-dichloroethane involves protonated DMFc, DMFcH(+), as an active intermediate species, producing hydrogen peroxide and hydrogen in aerobic and anaerobic conditions, respectively.
Permanent Link: http://hdl.handle.net/11104/0185399
Number of the records: 1