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Phase diagram of the sodium-rich Na.sub.x./sub.CoO.sub.2./sub. cobaltates
- 1.0342613 - FZÚ 2011 RIV DE eng J - Journal Article
Zorkovská, A. - Baran, A. - Kajňáková, M. - Feher, A. - Šebek, Josef - Šantavá, Eva - Lin, C. T. - Peng, J.B.
Phase diagram of the sodium-rich NaxCoO2 cobaltates.
Physica Status Solidi B. Roč. 247, č. 3 (2010), s. 665-667. ISSN 0370-1972. E-ISSN 1521-3951
Institutional research plan: CEZ:AV0Z10100520
Keywords : cobaltates * specific heat * magnetic phase transition * A-type antiferromagnetism
Subject RIV: BM - Solid Matter Physics ; Magnetism
Impact factor: 1.344, year: 2010
Specific heat of layered NaxCoO2 single crystals (x=0.76–0.87) down to 100mK and the dc-susceptibility down to 2K in magnetic field applied parallel to the layers has been measured. Non-Fermi liquid (NFL) features observed in Na concentration dependent temperature region have been analyzed and discussed in terms of disorder induced NFL behavior with quantum Griffiths phases in the background. The phase diagram is proposed, the results indicate possible quantum critical point below x=0.7 and closeness to metal–insulator transition at doping above x=0.87.
Permanent Link: http://hdl.handle.net/11104/0185304
Number of the records: 1