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Alkoxide-induced nucleophilic trifluoromethylation using diethyl trifluoromethylphosphonate

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    0342580 - ÚOCHB 2011 RIV GB eng J - Journal Article
    Cherkupally, Prabhakar - Beier, Petr
    Alkoxide-induced nucleophilic trifluoromethylation using diethyl trifluoromethylphosphonate.
    Tetrahedron Letters. Roč. 51, č. 2 (2010), s. 252-255. ISSN 0040-4039. E-ISSN 1873-3581
    R&D Projects: GA ČR GP203/08/P310
    Institutional research plan: CEZ:AV0Z40550506
    Keywords : trifluoromethylation * phosphonate * nucleophilic addition
    Subject RIV: CC - Organic Chemistry
    Impact factor: 2.618, year: 2010

    A novel alkoxide-induced nucleophilic trifluoromethylation of carbonyl compounds, disulfides and diselenides using diethyl trifluoromethylphosphonate is presented. In these reactions diethyl trifluoromethylphosphonate acts as a [CF3] synthon.
    Permanent Link: http://hdl.handle.net/11104/0185281

     
     
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