Recent Advances in Catalysis Over Mesoporous Molecular Sieves

0341712 - ÚFCH JH 2011 RIV NL eng J - Journal Article
Martín-Aranda, R. M. - Čejka, Jiří
Recent Advances in Catalysis Over Mesoporous Molecular Sieves.
Topics in Catalysis. Roč. 53, 3-4 (2010), s. 141-153. ISSN 1022-5528. E-ISSN 1572-9028
R&D Projects: GA AV ČR KAN100400701; GA AV ČR IAA400400805; GA ČR GA104/09/0561
Institutional research plan: CEZ:AV0Z40400503
Keywords : mesoporous molecular sieves * MCM-41 * SBA-15 * mesoporous alumina
Subject RIV: CF - Physical ; Theoretical Chemistry
Impact factor: 2.359, year: 2010

This overview covers the recent achievements in the application of mesoporous molecular sieves as catalysts and catalyst supports. Main structural and textural features are outlined in relation to the novel synthesis approaches of mesoporous molecular sieves and understanding of their properties. For application of mesoporous molecular sieves as catalysts different ways of introduction of active sites on their surfaces are provided. The main part describes selected catalytic reactions catalyzed by mesoporous molecular sieves focused on very recent papers. The examples include metathesis, acylation reactions, C-C coupling reactions of Heck and Suzuki types, base-catalyzed reactions (Knoevenagel and Michael additions, Claisen-Schmidt condensation, Tischenko reaction) and last but not least immobilization of organometallic complexes for different catalytic applications including chiral catalysts.
Permanent Link: http://hdl.handle.net/11104/0184610