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Alkyne-promoted H-2 loss in a metallaborane: nido-to-closo cluster transformation and sp C-H Bbnd oxidative addition
- 1.0340321 - ÚACH 2010 RIV DE eng J - Journal Article
Álvarez, A. - Macias, R. - Bould, Jonathan - Cunchillos, C. - Lahoz, F.J. - Oro, L.A.
Alkyne-promoted H-2 loss in a metallaborane: nido-to-closo cluster transformation and sp C-H Bbnd oxidative addition.
Chemistry - A European Journal. Roč. 15, č. 22 (2009), s. 5428-5431. ISSN 0947-6539. E-ISSN 1521-3765
R&D Projects: GA AV ČR(CZ) IAA400320601
Institutional research plan: CEZ:AV0Z40320502
Keywords : alkyne ligands * boranes * cluster compounds
Subject RIV: CA - Inorganic Chemistry
Impact factor: 5.382, year: 2009
The proposed catalytic cycle involves a full cluster participation with the matallacarborane cluster acting both as a source and a sinj for electrons and for dihydrogen trough nido-closo-nido cluster transformations.
Permanent Link: http://hdl.handle.net/11104/0183588
Number of the records: 1