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Deoxygenation of Vegetable Oils over Sulfided Ni, Mo and NiMo Catalysts

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    0335747 - ÚCHP 2010 RIV NL eng J - Journal Article
    Kubička, D. - Kaluža, Luděk
    Deoxygenation of Vegetable Oils over Sulfided Ni, Mo and NiMo Catalysts.
    Applied Catalysis A - General. Roč. 372, č. 2 (2010), s. 199-208. ISSN 0926-860X. E-ISSN 1873-3875
    R&D Projects: GA MPO FT-TA3/074
    Institutional research plan: CEZ:AV0Z40720504
    Keywords : deoxygenation * hydrodeoxygenation * biofuels
    Subject RIV: CC - Organic Chemistry
    Impact factor: 3.383, year: 2010

    The work focuses on investigation of Ni, Mo and NiMo sulfided catalysts in conversion of triglycerides to hydrocarbons. Their activity decreased in the order NiMo/Al2O3 > Mo/Al2O3 > Ni/Al2O3. NiMo catalysts were the most selective to hydrocarbons. Apart from oxygenated intermediates, NiMo/Al2O3 yielded hydrocarbons via decarboxylation and hydrodeoxygenation while Ni/Al2O3 yielded hydrocarbons via decarboxylation and Mo/Al2O3 yielded hydrocarbons via hydrodeoxygenation.
    Permanent Link: http://hdl.handle.net/11104/0005649

     
     
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