Number of the records: 1
Correlation between catalytic activity and metal cation coordination: NO decomposition over Cu/zeolites
- 1.0333516 - ÚOCHB 2011 RIV DE eng J - Journal Article
Pulido, Maria Angeles - Nachtigall, P.
Correlation between catalytic activity and metal cation coordination: NO decomposition over Cu/zeolites.
ChemCatChem. Roč. 1, č. 4 (2009), s. 449-453. ISSN 1867-3880. E-ISSN 1867-3899
R&D Projects: GA MŠMT LC512
Institutional research plan: CEZ:AV0Z40550506
Keywords : deNOx * mechanism * DFT
Subject RIV: CF - Physical ; Theoretical Chemistry
Impact factor: 0.000, year: 2009
The catalytic activity of Cu/zeolites for NO removal depends on the metal cation coordination to the framework. The most active catalysts are those with Cu+ loosely coordinated to the framework. The catalytic cycle is investigated using a periodic DFT model to account for the effect of the zeolite on the stability of reaction intermediates.
Permanent Link: http://hdl.handle.net/11104/0178477
Number of the records: 1