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Methyl 4-toluenesulfonyloxymethylphosphonate, a new and versatile reagent for the convenient synthesis of phosphonate-containing compounds

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    0332679 - ÚOCHB 2010 RIV GB eng J - Journal Article
    Markusová Kóšiová, Ivana - Točík, Zdeněk - Buděšínský, Miloš - Šimák, Ondřej - Liboska, Radek - Rejman, Dominik - Pačes, Ondřej - Rosenberg, Ivan
    Methyl 4-toluenesulfonyloxymethylphosphonate, a new and versatile reagent for the convenient synthesis of phosphonate-containing compounds.
    Tetrahedron Letters. Roč. 50, č. 49 (2009), s. 6745-6747. ISSN 0040-4039. E-ISSN 1873-3581
    R&D Projects: GA ČR GA202/09/0193; GA ČR GA203/09/0820; GA MŠMT(CZ) LC06061; GA MŠMT(CZ) LC06077; GA AV ČR KAN200520801
    Institutional research plan: CEZ:AV0Z40550506
    Keywords : nucleoside phosphonates * phosphonylation * methyl 4-toluenesulfonyloxymethylphosphonate
    Subject RIV: CC - Organic Chemistry
    Impact factor: 2.660, year: 2009

    A convenient procedure leading to new phosphonylating reagent, requiring no chromatographic purification, is described. This stable reagent is efficient in phosphonylations and causes no unwanted methylation in nucleoside molecule.
    Permanent Link: http://hdl.handle.net/11104/0177860

     
     
Number of the records: 1  

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