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Bio- and air-tolerant carbon–carbon bond formations via organometallic ruthenium catalysis

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    0330570 - ÚOCHB 2010 RIV CZ eng J - Journal Article
    Adriaenssens, Louis - Severa, Lukáš - Vávra, Jan - Šálová, Tereza - Hývl, Jakub - Čížková, Martina - Pohl, Radek - Šaman, David - Teplý, Filip
    Bio- and air-tolerant carbon–carbon bond formations via organometallic ruthenium catalysis.
    Collection of Czechoslovak Chemical Communications. Roč. 74, 7/8 (2009), s. 1023-1034. ISSN 0010-0765
    R&D Projects: GA ČR GA203/09/0705; GA ČR GA203/09/1614
    Institutional research plan: CEZ:AV0Z40550506
    Keywords : ruthenium * organometallic catalysis * C-C coupling * [2+2+2]cycloadditions
    Subject RIV: CC - Organic Chemistry
    Impact factor: 0.856, year: 2009

    Selected [2+2+2] cycloadditions, alkene-alkyne coupling and fusion of enyne with diazo compound, all triggered by an artificial organometallic ruthenium catalyst are demonstrated to proceed under ambient aerobic aqueous conditions in presence of bodily fluids or cell lysate. These are rare examples of bio- and air-tolerant C-C bond formation catalyzed by an artificial organometallic compound.
    Permanent Link: http://hdl.handle.net/11104/0176330

     
     
Number of the records: 1  

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