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Can Electrospray Mass Spectrometry Probe Speciation? Hydrolysis of Uranyl Nitrate Studied by Gas-Phase Methods
- 1.0329546 - ÚOCHB 2010 RIV US eng J - Journal Article
Tsierkezos, Nikos - Roithová, Jana - Schröder, Detlef - Ončák, Milan - Slavíček, Petr
Can Electrospray Mass Spectrometry Probe Speciation? Hydrolysis of Uranyl Nitrate Studied by Gas-Phase Methods.
Inorganic Chemistry. Roč. 48, č. 13 (2009), s. 6287-6296. ISSN 0020-1669. E-ISSN 1520-510X
R&D Projects: GA ČR GA203/08/1487
Grant - others:GA ČR(CZ) GP203/07/P449
Institutional research plan: CEZ:AV0Z40550506; CEZ:AV0Z40400503
Keywords : collision-induced dissociation * electrodpray ionization * ion association * mass spectrometry
Subject RIV: CF - Physical ; Theoretical Chemistry
Impact factor: 4.657, year: 2009
Electrospray ionization of uranyl nitrate dissolved in water leads to the contact-ion pairs [UO2(OH)]+ and [UO2(NO3)]+ solvated by up to four water molecules. The dependences of the ion intensities from the concentrations lead to a quantitative correlation between the gas-phase and solution-phase data.
Permanent Link: http://hdl.handle.net/11104/0005453
Number of the records: 1