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Gas-phase model studies relevant to the decomposition of transition-metal nitrates M(NO3)2 into metal-oxo species

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    0326744 - ÚOCHB 2010 RIV DE eng J - Journal Article
    Schröder, Detlef - De Jong, K. P. - Roithová, J.
    Gas-phase model studies relevant to the decomposition of transition-metal nitrates M(NO3)2 into metal-oxo species.
    European Journal of Inorganic Chemistry. -, č. 14 (2009), s. 2121-2128. ISSN 1434-1948. E-ISSN 1099-0682
    R&D Projects: GA ČR GA203/08/1487
    Institutional research plan: CEZ:AV0Z40550506
    Keywords : cobalt nitrate * cobalt oxide * electrospray ionization * nickel nitrate * nickel oxide
    Subject RIV: CF - Physical ; Theoretical Chemistry
    Impact factor: 2.941, year: 2009

    Electrospray ionization of aqueous cobalt(II) and nickel(II) nitrate solutions affords the solvated nitrato complexes [Mm(NO3)2m-1(H2O)n]+ (M = Co, Ni; m = 1 - 5; n = 1 - 4). Thermal reactions with nitrogen monoxide shed light on the NO-assisted pyrolysis of solid metal nitrates for the preparation of metal-oxide catalysts.
    Permanent Link: http://hdl.handle.net/11104/0173753

     
     
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