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Reactions of the dications C7H62+, C7H72+, and C7H82+ with methane: Predominance of doubly charged intermediates

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    0326568 - ÚOCHB 2010 RIV NL eng J - Journal Article
    Roithová, J. - Ricketts, Claire - Schröder, Detlef
    Reactions of the dications C7H62+, C7H72+, and C7H82+ with methane: Predominance of doubly charged intermediates.
    International Journal of Mass Spectrometry. Roč. 280, 1/3 (2009), s. 32-37. ISSN 1387-3806. E-ISSN 1873-2798
    Institutional research plan: CEZ:AV0Z40550506
    Keywords : bond forming reactions * dications * DFT calculations * electron transfer * hydride transfer
    Subject RIV: CC - Organic Chemistry
    Impact factor: 2.117, year: 2009

    The reactions of methane with the dications C7H62+, C7H72+, and C7H82+ generated by electron ionization of toluene are studied by mass spectrometry. It is shown that the reactivity is dominated by the formation of doubly charged intermediates.
    Permanent Link: http://hdl.handle.net/11104/0173633

     
     
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