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Hydrated metal-oxide versus dihydroxide structures of [MO2H2]+ cations with M=Fe, Co, and Ni
- 1.0326528 - ÚOCHB 2010 RIV NL eng J - Journal Article
Schröder, Detlef - Souvi, S. O. - Alikhani, E.
Hydrated metal-oxide versus dihydroxide structures of [MO2H2]+ cations with M=Fe, Co, and Ni.
Chemical Physics Letters. Roč. 470, 4/6 (2009), s. 162-165. ISSN 0009-2614. E-ISSN 1873-4448
R&D Projects: GA ČR GA203/08/1487
Institutional research plan: CEZ:AV0Z40550506
Keywords : cobalt oxide * electrospray ionization * mass spectrometry * metal nitrates * nickel oxide
Subject RIV: CF - Physical ; Theoretical Chemistry
Impact factor: 2.291, year: 2009
The formal metal(III) cations [CoO2H2]+ and [NiO2H2]+ are generated by electrospray ionization of aqueous solutions of the corresponding metal(II) nitrates. Experimental and theory predict Fe(OH)2+ to be more stable than (H2O)FeO+, whereas the opposite applies for M = Ni and both isomers are energetically close for M = Co.
Permanent Link: http://hdl.handle.net/11104/0005272
Number of the records: 1